(78).Weathering.

Vocabulary

abrasion

chemical weathering

climate

hydrolysis

ice wedging

leaching

mechanical weathering

oxidation

Introduction

The footprints that astronauts left on the Moon will be there forever. Why? This is because the Moon has no atmosphere and, as a result, has no weathering. Weathering is one of the forces on Earth that destroy rocks and landforms. Without weathering, geologic features would build up but would be less likely to break down.

What is Weathering?

Weathering is the process that changes solid rock into sediments. Sediments were described in the Rocks chapter. With weathering, rock is disintegrated. It breaks into pieces.

Once these sediments are separated from the rocks, erosion is the process that moves the sediments. Erosion is the next chapter's topic. The four forces of erosion are water, wind, glaciers, and gravity.

Water is responsible for most erosion. Water can move most sizes of sediments, depending on the strength of the force.

Wind moves sand-sized and smaller pieces of rock through the air.

Glaciers move all sizes of sediments, from extremely large boulders to the tiniest fragments.

Gravity moves broken pieces of rock, large or small, downslope.

While plate tectonics forces work to build huge mountains and other landscapes, the forces of weathering gradually wear those rocks and landscapes away. Together with erosion, tall mountains turn into hills and even plains. The Appalachian Mountains along the east coast of North America were once as tall as the Himalayas.

No human being can watch for millions of years as mountains are built, nor can anyone watch as those same mountains gradually are worn away. But imagine a new sidewalk or road. The new road is smooth and even. Over hundreds of years, it will completely disappear, but what happens over one year? What changes would you see (Figure below)? What forces of weathering wear down that road, or rocks or mountains over time?

Animations of different types of weathering processes can be found here: http://www.geography.ndo.co.uk/animationsweathering.htm#.

[Figure 1]

A once smooth road surface has cracks and fractures, plus a large pothole.

Mechanical Weathering

Mechanical weathering (also called physical weathering) breaks rock into smaller pieces. These smaller pieces are just like the bigger rock, just smaller. That means the rock has changed physically without changing its composition. The smaller pieces have the same minerals, in just the same proportions as the original rock.

There are many ways that rocks can be broken apart into smaller pieces. Ice wedging is the main form of mechanical weathering in any climate that regularly cycles above and below the freezing point (Figure below). Ice wedging works quickly, breaking apart rocks in areas with temperatures that cycle above and below freezing in the day and night, and also that cycle above and below freezing with the seasons.

[Figure 2]

Ice wedging.

Ice wedging breaks apart so much rock that large piles of broken rock are seen at the base of a hillside, as rock fragments separate and tumble down. Ice wedging is common in Earth’s polar regions and mid latitudes, and also at higher elevations, such as in the mountains. Abrasion is another form of mechanical weathering. In abrasion, one rock bumps against another rock.

Gravity causes abrasion as a rock tumbles down a mountainside or cliff.

Moving water causes abrasion as particles in the water collide and bump against one another.

Strong winds carrying pieces of sand can sandblast surfaces.

Ice in glaciers carries many bits and pieces of rock. Rocks embedded at the bottom of the glacier scrape against the rocks below.

Abrasion makes rocks with sharp or jagged edges smooth and round. If you have ever collected beach glass or cobbles from a stream, you have witnessed the work of abrasion (Figurebelow).

[Figure 3]

Rocks on a beach are worn down by abrasion as passing waves cause them to strike each other.

Now that you know what mechanical weathering is, can you think of other ways it could happen? Plants and animals can do the work of mechanical weathering (Figure below). This could happen slowly as a plant’s roots grow into a crack or fracture in rock and gradually grow larger, wedging open the crack. Burrowing animals can also break apart rock as they dig for food or to make living spaces for themselves.

[Figure 4]

(a) Human activities are responsible for enormous amounts of mechanical weathering, by digging or blasting into rock to build homes, roads, subways, or to quarry stone. (b) Salt weathering of building stone on the island of Gozo, Malta.

Mechanical weathering increases the rate of chemical weathering. As rock breaks into smaller pieces, the surface area of the pieces increases Figurebelow. With more surfaces exposed, there are more surfaces on which chemical weathering can occur.

[Figure 5]

Mechanical weathering may increase the rate of chemical weathering.

Chemical Weathering

Chemical weathering is the other important type of weathering. Chemical weathering is different from mechanical weathering because the rock changes, not just in size of pieces, but in composition. That is, one type of mineral changes into a different mineral. Chemical weathering works through chemical reactions that cause changes in the minerals.

Most minerals form at high pressure or high temperatures deep in the crust, or sometimes in the mantle. When these rocks reach the Earth’s surface, they are now at very low temperatures and pressures. This is a very different environment from the one in which they formed and the minerals are no longer stable. In chemical weathering, minerals that were stable inside the crust must change to minerals that are stable at Earth’s surface.

Remember that the most common minerals in Earth’s crust are the silicate minerals. Many silicate minerals form in igneous or metamorphic rocks. The minerals that form at the highest temperatures and pressures are the least stable at the surface. Clay is stable at the surface and chemical weathering converts many minerals to clay (Figurebelow).

[Figure 6]

Deforestation in Brazil reveals the underlying clay-rich soil.

There are many types of chemical weathering because there are many agents of chemical weathering. Water is the most important agent of chemical weathering. Two other important agents of chemical weathering are carbon dioxide and oxygen.

Chemical Weathering by Water

A water molecule has a very simple chemical formula, H₂O, two hydrogen atoms bonded to one oxygen atom. But water is pretty remarkable in terms of all the things it can do. Remember from the Earth's Minerals chapter that water is a polar molecule. The positive side of the molecule attracts negative ions and the negative side attracts positive ions. So water molecules separate the ions from their compounds and surround them. Water can completely dissolve some minerals, such as salt.

Hydrolysis is the name of the chemical reaction between a chemical compound and water. When this reaction takes place, water dissolves ions from the mineral and carries them away. These elements have undergone leaching. Through hydrolysis, a mineral such as potassium feldspar is leached of potassium and changed into a clay mineral. Clay minerals are more stable at the Earth’s surface.

Chemical Weathering by Carbon Dioxide

Carbon dioxide (CO₂) combines with water as raindrops fall through the atmosphere. This makes a weak acid, called carbonic acid. Carbonic acid is a very common in nature where it works to dissolve rock. Pollutants, such as sulfur and nitrogen, from fossil fuel burning, create sulfuric and nitric acid. Sulfuric and nitric acids are the two main components of acid rain, which accelerate chemical weathering (Figurebelow). Acid rain is discussed in the Human Actions and the Atmosphere chapter.

[Figure 7]

This statue has been damaged by acid rain.

Chemical Weathering by Oxygen

Oxidation is a chemical reaction that takes place when oxygen reacts with another element. Oxygen is very strongly chemically reactive. The most familiar type of oxidation is when iron reacts with oxygen to create rust (Figure below). Minerals that are rich in iron break down as the iron oxidizes and forms new compounds. Iron oxide produces the red color in soils.

[Figure 8]

When iron rich minerals oxidize, they produce the familiar red color found in rust.

Now that you know what chemical weathering is, can you think of some other ways chemical weathering might occur? Chemical weathering can also be contributed to by plants and animals. As plant roots take in soluble ions as nutrients, certain elements are exchanged. Plant roots and bacterial decay use carbon dioxide in the process of respiration.

Influences on Weathering

Weathering rates depend on several factors. These include the composition of the rock and the minerals it contains as well as the climate of a region.

Rock and Mineral Type

Different rock types weather at different rates. Certain types of rock are very resistant to weathering. Igneous rocks, especially intrusive igneous rocks such as granite, weather slowly because it is hard for water to penetrate them. Other types of rock, such as limestone, are easily weathered because they dissolve in weak acids.

Rocks that resist weathering remain at the surface and form ridges or hills. Devil’s Tower in Wyoming is an igneous rock from beneath a volcano (Figurebelow). As the surrounding less resistant rocks were worn away, the resistant center of the volcano remained behind.

[Figure 9]

Devil’s Tower is the central plug of resistant lava from which the surrounding rock weathered and eroded away.

Different minerals also weather at different rates. Some minerals in a rock might completely dissolve in water but the more resistant minerals remain. In this case, the rock’s surface becomes pitted and rough. When a less resistant mineral dissolves, more resistant mineral grains are released from the rock.

Climate

A region’s climate strongly influences weathering. Climate is determined by the temperature of a region plus the amount of precipitation it receives. Climate is weather averaged over a long period of time. Chemical weathering increases as:

Temperature increases: Chemical reactions proceed more rapidly at higher temperatures. For each 10^oC increase in average temperature, the rate of chemical reactions doubles.

Precipitation increases: More water allows more chemical reactions. Since water participates in both mechanical and chemical weathering, more water strongly increases weathering.

So how do different climates influence weathering? A cold, dry climate will produce the lowest rate of weathering. A warm, wet climate will produce the highest rate of weathering. The warmer a climate is, the more types of vegetation it will have and the greater the rate of biological weathering (Figure below). This happens because plants and bacteria grow and multiply faster in warmer temperatures.

[Figure 10]

Wet, warm tropical areas have the most weathering.

Some resources are concentrated by weathering processes. In tropical climates, intense chemical weathering carries away all soluble minerals, leaving behind just the least soluble components. The aluminum oxide, bauxite, forms this way and is our main source of aluminum ore.

Lesson Summary

Mechanical weathering breaks rocks into smaller pieces without changing their composition.

Ice wedging and abrasion are two important processes of mechanical weathering.

Chemical weathering breaks down rocks by forming new minerals that are stable at the Earth's surface.

Water, carbon dioxide, and oxygen are important agents of chemical weathering.

Different types of rocks weather at different rates. More resistant types of rocks will remain longer.